By Ruijun Hou
This thesis bargains novel equipment for catalyst and method layout for the selective hydrogenation of acetylene and 1,3-butadiene. the writer predicts the homes of supported Pd–Ni bimetallic catalysts utilizing density useful idea (DFT) calculations and temperature-programmed desorption (TPD). the superb correlation among version surfaces and supported catalysts demonstrates the feasibility of designing powerful bimetallic catalysts for selective hydrogenation reactions. the writer additionally proposes a style for designing non-precious steel catalysts to exchange helpful metals. she alters the method of selective hydrogenation of acetylene through coupling the selective adsorption to the selective hydrogenation within the liquid part, because of which the ethylene selectivity is drastically stronger and warmth move is significantly more desirable. finally, via studying the mechanism of liquid-phase hydrogenation, the writer proposes a multi-stage slurry mattress reactor for commercial applications.<
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Extra info for Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene (Springer Theses)
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene (Springer Theses) by Ruijun Hou